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Specialty Coatings: Protecting Against Electromagnetic Emissions

Posted on November 25, 2016 by Marc Hirsch — Leave a Comment

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Learn about the applications of electrically conductive specialty coatings in the Prospector Knowledge Center.
Copyright: nexusplexus / 123RF Stock Photo

EMI shielding, thermal and electrical conductivity, electro dissipation – these type of specialty coatings are sometimes classified under the general heading of “smart” coatings. However, I define “smart” as coatings that respond “intelligently” to various mechanical, electrical, thermal and optical stimuli, and don’t feel these fit in the category. An excellent article, “Smart Coatings: The Next Big Opportunity in the Coatings Industry”1 can be found in Paint & Coatings Industry magazine.

Electromagnetic Compatibility and Interference

Electromagnetic compatibility (EMC) means an electronics device will perform according to the rated specification in its electromagnetic environment.

Electromagnetic Interference (EMI) occurs when an external source disrupts an electrical circuit by electromagnetic induction, electrostatic coupling, or conduction. Electromagnetic interference can be categorized in two ways:

  • Broadband is unintentional radiation from sources such as electric power transmission lines and other high voltage electrical devices, electronic instrumentation and generators
  • Narrowband EMI, which transpires from radio and TV stations or cell phones, happens intentionally.

Additional sources include: transmitters, doorbell transformers, toaster ovens, electric blankets, microwaves and touch controlled lamps. Electromagnetic interference at 2.4 GHz can be caused by 802.11b and 802.11g wireless devices, Bluetooth devices, baby monitors, cordless telephones, video senders, and microwave ovens.

EMI Shielding

Learn about "smart" specialty coatings from Marc Hirsch on Prospector Knowledge Center.
Figure 1. Shielding screen can shield the radiation from mobile, radios2

Since 1979, the U.S. Federal Communications Commission (FCC) has imposed legal limits on electromagnetic emissions from all digital equipment in response to the increased number of digital systems that interfere with radio communications.

In addition, as analytical and other sensitive equipment became more sophisticated and delicate, these devices required protection from external sources of electromagnetivity which would affect the performance.

Although there have been methods to dampen the effect of EMI for many years, these included the use of metallic (often copper) Faraday cages (Figure 1), which are actually mesh structures. In the case of analytical labs, these had to be built in to the walls, which has led to the search for more cost-effective and simpler methods.

The discovery of single- and multi-walled nanotubes as well as other conductive, carbonaceous materials, has led to the next generation of EMI-shielding materials. Metals such as copper, silver, nickel and nickel-plated carbon fibers, are also used in coatings, sealants and gaskets to mitigate or eliminate EMI, as well as dissipate Electrostatic Discharge (ESD)3. Other materials are also used, including conductive paints, sealants, and composites.

Beyond Electronics

Besides the obvious applications for electronics, EMI-shielding materials can also be employed to reduce the radar signature of vehicles such as aircraft, ships and ground vehicles. This, along with specific shapes, have enabled the military to effectively and wholly hide structures from radar detection. They can also be used to protect rooms from eavesdropping; which often use enhanced listening devices.

In the metallic coating solution, it has to be filled sufficiently enough such that the particles are in close proximity to one another and touch. This means small particles, or a distribution to minimize volume voids, which then can affect rheology, etc.

With carbonaceous materials, they also have to touch, but are less dense, and in the case of single- or multi-walled nanotubes, can be effective at a relatively low loading in coatings, including paints, sealants and adhesives.

Thermal and Electrical Conductivity

In some ways, electrical and thermal conductivity are similar. The types of technologies to achieve each in coatings can be comparable. Both are presented here, but an article in Coatings Tech, “Being Creative with Electrically Conductive Paint”4 offers a thorough explanation of the latter, should you want a more complete overview.

Over the past several years, electrically conductive inks and paints have been developed to replace wiring in printed circuit board circuitry, which has helped decrease production costs and makes many electronic devices affordable.

Thermal conductivity is important in mitigating heat build-up or removing heat as quickly as possible. One specific example is in air conditioning. Coils are typically copper, while the fins are aluminum. An increase in heat removal from the fins and coils will increase the efficiency of the heat exchange by 5-15 percent, thus reducing operating costs. For large (e.g. 20 ton) units, this translates to hundreds of thousands of dollars annually.

On the other end of the spectrum is non-conductivity (insulation). This is the key to maintaining the temperature in equipment like an oven, refractory, or gas turbine. Many of these are ceramic-based, since they deploy high temperatures, and ceramic or glass microspheres provide an insulating air void.

Electrostatic Dissipation (aka Electrostatic Discharge)

When you walk across a carpet in a dry room and touch a metal object, static creates a spark. If the metal object you touched was a sensitive instrument, you may damage it, or throw off its calibration. For that reason, it is important to dissipate the charge, so it doesn’t create a spark. Lightning is an extreme case of electrostatic dissipation as it hits an object on the ground. Sometimes a discharge is desired, as in corona discharge, which may be used to treat the surface of plastics to improve adhesion of an applied coating.

Sparks around flammable gasses, medical equipment, integrated circuits, etc. are highly undesirable. For that reason, various techniques are utilized such as grounding, or ESD. Measures to eliminate the potential for sparks include grounding human workers, providing antistatic devices, and controlling humidity. Many sites utilize floor mats at the entranceways to areas of high sensitivity, but coatings can also be used to mitigate and eliminate the generation of small electrical discharges.

In summary, these applications areas for coatings are not well-known, but very important to the markets in which they are used.

References:

  1. “Smart coatings: the next big opportunity in the coatings industry”
  2. Shielding Screen information
  3. Conductive Shielding Paint Application
  4. “Being Creative with Electrically Conductive Paint”

The views, opinions and technical analyses presented here are those of the author, and are not necessarily those of UL, ULProspector.com or Knowledge.ULProspector.com. While the editors of this site make every effort to verify the accuracy of its content, we assume no responsibility for errors made by the author, editorial staff or any other contributor. All content is subject to copyright and may not be reproduced without prior authorization from Prospector.

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Filed Under: Paint & Coatings Tagged With: coatings, Formulating Advice

About Marc Hirsch

Mr. Hirsch is a Senior Development Scientist and Principal Consultant at M&M Hirsch & Associates. In his career, he has formulated architectural, industrial, military and specialty coatings. He developed applications and methodologies for sol gel coatings, and has earned his Green Belt in MAIC Six Sigma and trained for MAIC Black Belt. He has applied MAIC methodology to the CTR for several laboratory and manufacturing processes in the coatings industry, resulting in substantial savings. In addition, he has written more than $4M in proposals through the SBIR process for the DoD, DoE and more than $145M of proposals for fossil and nuclear power plant simulation.

He has successfully facilitated numerous ideation teams within his expertise, as well as outside his core competencies. These included cross-functional and cross-business groups. Prior to his current position, he worked at GE Energy (2008-2011) in the Simulation group writing proposals to published specifications for training simulators for both fossil and nuclear power plants.

From 2004-2008 he was a Developmental Scientist in the Advanced Materials group at Luna Innovations. Previously, he was at Dow Chemical (1995-2004) as the applications and development manager in Core R&D in the Coatings & Functional Polymers Group. He also managed the TS&D group for coatings while at Dow (1995-99) and held positions at Rhodia (Laboratory Manager, Latex & Specialty Polymers (1989-95)) and was the Development Chemist, exterior latex paints at Benjamin Moore & Co. (1979-82).

Mr. Hirsch consults with organizations to provide mentoring, coaching and leadership training, as well as the facilitation of problem solving teams. He has several granted patents, many patent applications and internal disclosures for trade secrets.

Specialties

  • Coatings formulations and applications.
  • Team-building, mentoring and facilitation of global multifunctional project teams.
  • Portfolio management.
  • Six sigma implementation.
  • Market-focused innovation with sustainable value.
  • Developing, transforming, and leading high performance, global R&D organizations.
  • Business strategy development and implementation.
  • Talent development and engagement.
  • Strategic development of core competencies.

Type of teams/projects managed and facilitated:

  • Coatings: Paints, inks, adhesives, construction products and all raw materials included in those markets (resins, pigments, etc)
  • Development and launch of internal internet mentoring for a 300+ person R&D organization
  • Color perception in excipient coatings for pharma tablets
  • Fast-setting cationic polymers
  • Novel waterborne corrosion-resistant conformal coating
  • Defoamer/anti-foam development through scale-up
  • Thermal cure Solgel coatings for scratch resistance
  • Novel self-decontaminating surface coating (high water retention to germinate and the kill anthrax spores)
  • Evaluation of the potential synergies of company X’s collective businesses for the wood products’ market
  • Technical cross-functional/product team – Coatings Applications Development Center
  • Conductive coatings based on nanotechnology
  • Solgel coating for water impermeability of ceramic missile nosecones
  • Impact indicating coating for composite materials (e.g. Hellfire Missiles)
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